COLLOID
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Understanding
Colloid
Colloids is a heterogeneous mixture of two or
more substances in which particle substances measuring between 1 and 1000 nm
are dispersed (distributed) evenly in the medium of another substance.
Substances dispersed as particles are called dispersed phases, whereas the
substance into the medium disperses the particles called the dispersing medium.
Macroscopically,
the colloid looks like a solution, in which a homogeneous mixture of solutes
and solvents is formed. However, microscopically, it looks like a suspension,
ie a heterogeneous mixture in which each of the mixed components tends to
separate each other.
Colloidal
Types
The
colloidal system can be grouped according to the dispersed phase and the
dispersing phase. Based on the dispersed phase, there are three colloid types,
among others sol (solid dispersed phase), emulsions (liquid dispersed phase),
and froth (gas dispersed phase). Colloids with a gas dispersing phase are
called aerosols.
Based
on the dispersed and dispersed phases, the colloidal type can be divided into 8
groups as in the following table.
Phase Dispersed
|
Phase Dispersing
|
Colloid Type
|
Colloidal Example
|
Liquid
|
Gas
|
Aerosol
|
Fog, cloud, hair spray
|
Solid
|
Gas
|
Aerosol
|
Asa, dust in the air
|
Gas
|
Liquid
|
The foam
|
Soap scum, whipped cream
|
Liquid
|
Liquid
|
Emulsion
|
Milk, coconut milk, mayonnaise
|
Solid
|
Liquid
|
Sol
|
Gold soles, ink, paint, toothpaste
|
Gas
|
Solid
|
Solid foam
|
Rubber foam, Styrofoam, pumice stone
|
Liquid
|
Solid
|
Solid emulsion (gel)
|
Margarine, cheese, jelly, pearl
|
Solid
|
Solid
|
Solid soles
|
Colored glass, black diamond
|
4.
Properties of Colloid

1.
Tyndall effect
When a beam of light is
directed to the solution, light is passed on. However, when the light beam is
directed to the colloidal system, the light will be scattered. The effect of
light scattering by colloidal particles is called the Tyndall effect.
2.
Brownian motion
Microscopically,
colloid particles move randomly with a zig-zag pathway in the dispersing
medium. This movement is caused by the occurrence of collisions between
colloidal particles with the dispersing medium. This random motion of particles
is called Brownian motion.
3.
Colloidal load
a.
Adsorption
Colloidal particles can
absorb other charged and uncharged particles on the surface. The absorption of
particles on the surface of these substances is called adsorption.
b.Electrophoresis
Colloidal particles can
move in an electric field. This shows that the colloid particles are
electrically charged. The movement of colloid particles in electric fields
where charged particles move toward the electrode with this opposite charge is
called electrophoresis.
4.Coagulation
Similar electrical
charges from colloidal particles help stabilize the colloidal system. If the
electrical charge is lost, the colloid particles will become unstable and
combine to form clots. The process of forming clumps of these particles is
called coagulation. Coagulation can be done in four ways, namely:
1. mechanical
2. using the principle
of electrophoresis
3. adding electrolyte
4. add another colloid
with opposite charge
Colloid
Making
1.
Colloid Making by Condensation
In this way, small
particles (solute particles) merge into larger particles (colloidal particles),
which can be done through:
1.
Redox reactions
Example: the
manufacture of sulfur sol
2H2S (g) + SO2 (aq) →
3S (colloid) + 2H2O (l)
2.
Hydrolysis
Example: making Fe Fe
(OH) 3 by adding FeCl3 solution to boiling water
FeCl3 (aq) + 3H2O (l) →
Fe (OH) 3 (colloid) + 3HCl (aq)
3.
Duplicate decomposition
Example: AgCl sole
manufacture
AgNO3 (aq) + HCl (aq) →
AgCl (colloid) + HNO3 (aq)
4. Solvent replacement
Example: when saturated
calcium acetate solution mixed with alcohol will form a colloid of gel
2.
Preparation of Colloid by Dispersion
In this way, large
particles (suspension particles) are broken down into smaller particles
(colloidal particles), which can be done through:
1.
Mechanical way
In this way, the coarse
grains are crushed or ground with a colloid grinder up to a certain degree of
fineness and then stirred in a dispersing medium. Example: sulfur sole can be
made by grinding sulfur powder together with sugar, then the finely ground
powder is mixed with water.
2.
How to peptisasi
In this way, large
particles are broken down with the aid of the perceptifier (breaker). Example:
Al (OH) 3 precipitated by AlCl3; Precipitate NiS by H2S; And agar is peppered
by water.
3.
How to Bredig arc
This method is used to
make metal soles such as Ag, Au, and Pt. The metal to be used as a colloid is
used as an electrode dipped in the dispersing medium and the two ends of the
electrode are electrically jumped
Explain why a solution can be called colloid?
BalasHapusFor example, if the gas is dispersed in a liquid medium, the colloids produced are foam (eg condensed milk). If two liquids are combined together, the resulting colloid is known as an emulsion (eg milk) .Particles distributed in colloidal medium are not Settling if left alone. Colloid solutions are clear or opaque.
Hapushow does the process of tyndall effect ? And explain the role of coagulation in life. ??
BalasHapusThe Tyndall effect is the effect that occurs when a solution is exposed to light. When the true solution is irradiated with light, the solution will not scatter light, whereas in the colloidal system light will be dissipated. This happens because colloidal particles have relatively large particles to scatter them. In contrast, in the true solution, the particles are relatively small so that the scattering occurs only slightly and is very difficult to observe.
HapusThe role of coagulation in everyday life
1. Addition of casein to milk,
2. Addition of lecithin to margarine,
3. Added gelatin to ice cream,
4. Adding silicone oil to the paint
Please give another example of Tyndall effect in daily life.
BalasHapusExamples of Tyndall Effects are as follows:
Hapus1.Slight a car light or flashlight in the foggy air
2. In the afternoon the appearance of blue and orange
3. Sunshine through the crevices of the leaves in the morning
Explain the difference of drill motion with absorption?
BalasHapusBrownian motion is the movement of colloid particles with a straight path and random direction, while Adsorption is the event of charge absorption by the surface of colloidal particles.
HapusWhat is the effect of Brownian motion on the colloidal system? Explain!
BalasHapusBrownian motion causes colloid particles to be relatively stable despite their relatively large size, because in the presence of continuously moving particles, the effect of gravitational forces is less meaningful.
BalasHapus